And Byakuya is probably close to 1k years I believe.
Assuming we're talking about only captains, I'd say Toushiro is about what, 300 years or so? Maybe less? He is a genius after all and Shunsui said that Toushiro would surpass him in atleast 100 years from what I recall.
Soi Fon(is this her name tbh? I actually don't remember. <-<), no idea either, probably 500 years old, maybe a bit more. The new captains(3rd, 5th and 9th divisions) are atleast more than one thousand years old, since they go way back till Kisuke was a captain.
The 8th division has no captain I believe? It was Aizen and he's like one thousand years old too I believe, maybe a couple of hundred of years since he was just about a kid during the hollowfication experiment, maybe more, dunno.
As for Korutsuchi, I'm pretty sure and confident that he's probably the same age as either Kisuke or pretty close to Unohana's.