Originally Posted by
MordorFires
Valor gear is double gated by needing Valor and reputation levels. Rep can be gained by dailies and also your first Heroic of the day and first Scenario. Also by planting quests at the Tillers farm at Halfhill Market in the Valley of the Four Winds. There are multiple daily hubs, the main ones being Golden Lotus, August Celestials, Klaxxi, and the Shado-pan. Another rep was added in 5.1 in Krasarang Wilds, faction-specific. Dominance Offensive for Horde, dunno what the Alliance one is. 5.2 added the Sunreavers for Horde, again don't know what Alliance one is, both on the Isle of Thunder, northwest of Townlong, portal to it near Shado-pan. Also of note, Shado-pan and August Celestials are gated behind getting to Revered with Golden Lotus.
When you hit 90, do Heroics and get 463s. Do dailies and get Valor, buy some 496 gear. Also get to whatever ilvl you need for Mogushan Vaults LFR (460?) and queue for that. At 470, queue for Heart of Fear and Terrace of Endless Spring LFR. At 480, queue for Throne of Thunder LFR.
Daily quests reward you with Lesser Charms, get 90 and turn them in for a weekly quest that gives you 3 Mogu Runes of Fate, which can be used for an extra roll when you kill a boss in Throne of Thunder. Charms for extra rolls on T14 bosses (Vaults, Heart of Fear, Terrace) can be gotten on the Isle of Thunder through a variety of means.
Most importantly, when you hit 90 and go to the Shrine of Two Moons in the Vale, you'll automatically get quests pointing you to most of these things. Course if your raid group only logs on for raid and has no interest in helping a fellow guildie find his way through MoP, I'd be a little worried about that to be honest.