Even though the show doesn't have much story continuity, character development makes a difference, so I would recommend whatever the next ones you haven't watched.
On top of that, some fan faves include S1EP16 "Sonic Rainboom", S1EP25 "Party of One", S1EP26 "The Best Night Ever", and most of season 2. The two-part season two premier features John de Lancie as basically a cartoon version of Q, known as Discord. "Luna Eclipsed" is a fan fave, but only if you're hardcore for Luna, and unless you followed the fandom for a while, you probably aren't.
https://dl.dropbox.com/u/73568185/tw...ybodywants.jpg
I put it on my dropbox to make it easier to link :x
Sig: Elyssia | DJoron is the Best
Sig: Elyssia | DJoron is the Best
Sig: Elyssia | DJoron is the Best
Kaname, to answer your question, yes, that scene is there in the first episode. But, you could argue, they didn't know each other then, and they were just huddling with the closest pony because they were scared. They may have remembered a face when they meet in Call of the Cutie, but really, they never introduced.
That said, I can't remember if the writers/artists said it was intentional.
Don't know what it's from, but I'm sure I stole it from one of y'all
---------- Post added 2012-10-23 at 10:50 PM ----------
I'm wondering if anyone remembers when this was posted in the thread, I think by Alatoic.
Sig: Elyssia | DJoron is the Best
I have 100 dollars to spend on clothes.
PARTY TIEM.