Can I let you in on a secret? You probably know it already. The entire mission was over engineered (not in a bad way). Their planned launch and development was a very conservative take on what the craft and rocket were capable of. The actual engineers and flight operators were fairly confident in everything up to this point. They've done so many tests, simulations, dry runs that they weren't worried really about anything but unknown unknowns, which you can't stress about.
There's rarely a NASA mission that doesn't end up with a ton of extra mission time. They are that cautious and forward thinking, for better or worse. Hats off to the ESA because the Ariane 5 isn't always recognized for being the marvel it is. It's not as big as a Delta IV, not as sexy as a Falcon 9, doesn't have the prestige of a Soyuz or Proton, but is a reliable work horse.