Amani War Bear: one of the best group experiences i had in early WoW
Ahead of the Curve Garrosh: The experiences about playing MoP and with the people ive met during this expansion are worth a lot to me.
Hunter MC class weapons: They were THE hunter artifact way before artifacts. loved doing it.
Both classic Zul'Gurub mounts: still use them a lot today, still proud.
Salty when winning the STV was required, solo, on a PvP server with groups of dedicated gankers helping other competitors. I'm fairly sure I wouldn't have made it without alchemy (invis and living action potions) and engineering (nitros). One guy's gank group especially must've regretted not having their warlock cast detect invisibility near the turn in, hah.
Breaker of the Black Harvest was also rather satisfying though nowhere near as challenging as some other stuff including the STV extravaganza.
Camel-Hoarder. Took me literally months and over 35 fake statues before I got the real one. It brought out some seriously obsessive behaviour in me - staying up late to check low-pop realms, making a map to track where and when I'd seen spawns - but it felt great to get. I use the title on my alts but not the mount.
AOTC: Garrosh, which I got by persistent pugging, having only started playing WoW in 5.4.
AOTC: Xavius, my first and to date only curve achievement from raiding with a guild.