Is everything plugged in properly? Check all the connectors are flush with the edge of the socket, there should be no gaps. Have you got the two 6pin PCI-E connectors plugged in to the GPU?
But I keep thinking that if it's my PSU overloading wouldn't it crash my comp. Also everything seems to be taking a little longer to open up & run properly since I installed the GPU & PSU.
Not to necro a thread or anything but I ended up finding the problem. My Bios were outdated & were causing boot up problems. Nothing with my PSU actually.