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Polarthief - For Legion, all of the trinkets on AMR are ranked directly from simulations, so that's a big improvement over WoD. IN WoD we tried to convert procs to a related damage stat so stat weights could rank them, and while it was clever, it wasn't good enough. So now, every single item with a proc gets ranked directly from simulations.
Keep in mind, the default stat weights also include default trinket sims - which are not custom to your character. If you run custom weights on our site, the trinkets will also get custom sims.
I've also spent a ton of time comparing our trinket sims to actual WCL logs to make sure they are accurate. So far so good. But if you see something off, definitely let me know so I can dig into it.