For whatever reason the PS4 / DS4 controller doesn't calibrate. Use this in the cfg.
Typically here: C:\Users\aaaaaaaaahhhhhhhhh\Documents\My Games\FINAL FANTASY XIV - A Realm Reborn
Alias {90,91,88,89,41,40,32,33,73,72,48,49,3,2,1,0,4,6,10,5,7,11,9,8}